Pal, Sunirmal ; De, Priyadarsi (2012) Water soluble polyperoxides from 2-(2-methoxyethoxy)ethyl methacrylate: influence of molecular oxygen on thermoresponsive properties and thermal degradation. Chemical Communications, 48 (35). p. 4229. ISSN 1359-7345
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Official URL: https://doi.org/10.1039/C2CC18013H
Related URL: http://dx.doi.org/10.1039/C2CC18013H
Abstract
The 2-(2-methoxyethoxy)ethyl methacrylate and molecular oxygen react at 50 °C under high pressure in the presence of a radical initiator to give water soluble, thermoresponsive poly(2-(2-methoxyethoxy)ethyl methacrylate) peroxide (PMEO2MAP), which degrades highly exothermically. The polymer structure has been confirmed by spectroscopy, elemental analysis, calorimetry and mass spectrometry.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 137961 |
| Deposited On: | 29 Aug 2025 07:29 |
| Last Modified: | 29 Aug 2025 07:29 |
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