Encapsulation induced aggregation: a self-assembly strategy for weakly pi-stacking chromophores.

Sao, Soumik ; Mukherjee, Ishita ; De, Priyadarsi ; Chaudhuri, Debangshu (2017) Encapsulation induced aggregation: a self-assembly strategy for weakly pi-stacking chromophores. Chemical Communications, 53 (28). pp. 3994-3997. ISSN 1359-7345

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Official URL: https://doi.org/10.1039/C7CC00554G

Related URL: http://dx.doi.org/10.1039/C7CC00554G

Abstract

Molecular assembly of weakly pi-stacking core-substituted naphthalene diimides (cNDIs) requires the participation of strong side-group interactions. Spatial confinement within a micellar core leads to locally elevated concentrations and reduced entropy that drives a rapid aggregation, often followed by a slower aggregate reorganization. Fast aggregation kinetics leads to self-sorting of aggregates.

Item Type:Article
Source:Copyright of this article belongs to Royal Society of Chemistry.
ID Code:137952
Deposited On:29 Aug 2025 07:07
Last Modified:29 Aug 2025 07:07

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