Reduction of 1,4-dichlorobut-2-yne by titanocene to a 1,2,3-butatriene. Formation of a 1-titanacyclopent-3-yne and a 2,5-dititanabicyclo[2.2.0]hex-1(4)-ene

Burlakov, Vladimir V. ; Arndt, Perdita ; Baumann, Wolfgang ; Spannenberg, Anke ; Rosenthal, Uwe ; Parameswaran, Pattiyil ; Jemmis, Eluvathingal D. (2004) Reduction of 1,4-dichlorobut-2-yne by titanocene to a 1,2,3-butatriene. Formation of a 1-titanacyclopent-3-yne and a 2,5-dititanabicyclo[2.2.0]hex-1(4)-ene Chemical Communications, 18 . pp. 2074-2075. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2004...

Related URL: http://dx.doi.org/10.1039/B406494A

Abstract

The 2,5-dititanabicyclo[2.2.0]hex-1(4)-ene (bis-titanocene-μ-(Z)-1,2,3-butatriene complex) (3) is formed starting from [Cp₂Ti(η²-Me₃SiC₂SiMe₃)] by in situ generated titanocene and 1,4-dichlorobut-2-yne via the 1-titanacyclobut-3-yne (2).

Item Type:	Article
Source:	Copyright of this article belongs to Royal Society of Chemistry.
ID Code:	13638
Deposited On:	12 Nov 2010 15:12
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