Mukherjee, Raka ; Bhunia, Prasenjit ; De, Sirshendu (2016) Impact of graphene oxide on removal of heavy metals using mixed matrix membrane Chemical Engineering Journal, 292 . pp. 284-297. ISSN 1385-8947
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Official URL: http://doi.org/10.1016/j.cej.2016.02.015
Related URL: http://dx.doi.org/10.1016/j.cej.2016.02.015
Abstract
The graphene oxide (GO) impregnated mixed matrix membrane (MMM) was prepared by non-solvent induced phase inversion method. MMM was characterized in terms of molecular weight cut-off, porosity, permeability, average pore size, pore size distribution, contact angle, zeta potential and mechanical strength. The membrane became highly permeable, hydrophilic and charged on addition of GO. The surface morphology and roughness were studied through scanning electron and atomic force microscopy. Efficacy of MMM for removal of heavy metals was explored using the developed MMM. It showed high adsorption capacity for Pb2+ (79 mg/g), Cu2+ (75 mg/g), Cd2+ (68 mg/g) and Cr6+ (154 mg/g) at natural pH, 6.7, 6.5, 6.4 and 3.5, respectively. The steady state permeate flux was around 30 l/m2 h for 50 mg/l feed concentration at 414 kPa transmembrane pressure drop and 40 l/h cross flow rate. Rejection of Pb, Cu, Cd and Cr were in between 90% and 96% for various operating conditions and the breakthrough time was around 10 h for different metal ions. The membrane was regenerated in-situ, by acidic solution at pH 5.5.
Item Type: | Article |
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Source: | Copyright of this article belongs to Elsevier Science. |
ID Code: | 136276 |
Deposited On: | 21 May 2025 07:42 |
Last Modified: | 21 May 2025 07:42 |
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