Addy, David A. ; Pierce, Glesni A. ; Vidovic, Dragoslav ; Mallick, Dibyendu ; Jemmis, Eluvathingal D. ; Goicoechea, Jose M. ; Aldridge, Simon (2010) Generation of cationic two-coordinate group-13 ligand systems by spontaneous halide ejection: remarkably nucleophile-resistant (dimethylamino)borylene complexes Journal of the American Chemical Society, 132 (13). pp. 4586-4588. ISSN 0002-7863
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ja101192e
Related URL: http://dx.doi.org/10.1021/ja101192e
Abstract
Spontaneous ejection of chloride from a three-coordinate boron Lewis acid can be effected by employing very electron rich metal substituents and leads to the formation of a sterically unprotected terminal (dimethylamino)borylene complex that has a short metal-boron bond and remarkable resistance to attack by nucleophilic and protic reagents.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 13598 |
| Deposited On: | 12 Nov 2010 15:16 |
| Last Modified: | 04 Jun 2011 04:15 |
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