Naga Srinivas, G. ; Srinivas, Hotha ; Jemmis, Eluvathingal D. (1994) Electronic structure study of the reactivity centres in Ti8C12 clusters Proceedings of the Indian Academy of Sciences - Chemical Sciences, 106 (2). pp. 169-181. ISSN 0253-4134
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Official URL: http://www.ias.ac.in/j_archive/chemsci/106/5/169-1...
Related URL: http://dx.doi.org/10.1007/BF02840741
Abstract
The reactivity centres of Ti8C12, for the three structures suggested in conformity with experimental observations, are studied by extended Huckel theory, The C2 unit can complex with transition metal fragments such as Pt(PH3)2 with the unusual net result of transferring two electrons to Ti8C12. The metal centre, Ti can accommodate extra two-electron donors like CO. Model systems are used to explain the carbon and metal environment in Ti8C12.
| Item Type: | Article |
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| Source: | Copyright of this article belongs to Indian Academy of Sciences. |
| Keywords: | Reactivity Centres; Ti8C12 Clusters; Extended Huckel Theory; Transition Metalfragments |
| ID Code: | 13588 |
| Deposited On: | 12 Nov 2010 15:17 |
| Last Modified: | 16 May 2016 22:44 |
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