Bulk, dense, nanocrystalline yttrium aluminum garnet by consolidation of amorphous powders at low temperatures and high pressures

Abstract

Amorphous Al₂O₃-37.5% Y₂O₃ powders, prepared using spray pyrolysis followed by partial or complete thermal decomposition, were hot-pressed at 315°-640°C and 500 or 750 MPa uniaxial pressure. Hot pressing of fully decomposed amorphous powder at 450°-640°C at pressures up to 750 MPa led to densification (up to 96%) as well as nanocrystallization of yttrium aluminum garnet (YAG). When the pressure was applied during heating, instead of after reaching the final temperature, higher relative densities resulted. Fully crystalline starting powder did not densify. The low true density of the amorphous phase (3.1 g·cm^-3) was believed to be responsible for the densification through enhanced ionic mobilities.