Divergent Enantioselective Total Synthesis of Siphonarienal, Siphonarienone, and Pectinatone

Yadav, Jhillu Singh ; Chary, D. Narasimha ; Yadav, Nagendra Nath ; Sengupta, Sandip ; Subba Reddy, Basi V. (2013) Divergent Enantioselective Total Synthesis of Siphonarienal, Siphonarienone, and Pectinatone Helvetica Chimica Acta, 96 (10). pp. 1968-1977. ISSN 0018-019X

Full text not available from this repository.

Official URL: http://doi.org/10.1002/Hlca.201300035

Related URL: http://dx.doi.org/10.1002/Hlca.201300035

Abstract

A divergent synthesis of siphonarienal, siphonarienone, and pectinatone has been achieved from a common precursor 4, which was synthesized by using an enzymatic desymmetrization approach. The major key steps involved were Grignard reaction, Wittig reaction, Evans' asymmetric alkylation, and base-catalyzed cyclization.

Item Type:Article
Source:Copyright of this article belongs to John Wiley & Sons, Inc.
ID Code:135752
Deposited On:14 Aug 2023 04:55
Last Modified:14 Aug 2023 04:55

Repository Staff Only: item control page