Yadav, J. S. ; Nayak, Sambit ; Sabitha, G. (2013) Stereoselective synthesis of the C15–C30 subunit of dolabelides A–D RSC Advances, 3 (43). p. 21007. ISSN 2046-2069
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Official URL: http://doi.org/10.1039/C3RA44232B
Related URL: http://dx.doi.org/10.1039/C3RA44232B
Abstract
A highly stereoselective synthesis of the C15–C30 subunit of the cytotoxic macrolides dolabelides A–D has been accomplished by utilizing anti selective aldol reaction, Wittig olefination for the introduction of a trisubstituted (E)-double bond, selective hydroboration, Brown asymmetric allylation, Wilkinson hydrogenation and stereoselective keto reduction for the installation of C19 hydroxy group as key steps.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 135742 |
| Deposited On: | 11 Aug 2023 09:26 |
| Last Modified: | 11 Aug 2023 09:26 |
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