Mohapatra, Debendra K. ; Kanikarapu, Suresh ; Naidu, P. Ramesh ; Yadav, Jhillu S. (2015) Toward the synthesis of brevipolide H Tetrahedron Letters, 56 (8). pp. 1041-1044. ISSN 0040-4039
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Official URL: http://doi.org/10.1016/J.Tetlet.2014.12.125
Related URL: http://dx.doi.org/10.1016/J.Tetlet.2014.12.125
Abstract
A linear diastereoselective synthesis of C1–C12 fragment of brevipolide H is described. The key reactions include Jørgensen’s asymmetric epoxidation, palladium-catalyzed regioselective opening of α,β-unsaturated γ,δ-epoxide, Charette’s modified Simmons–Smith cyclopropanation, anti-selective reduction of cyclopropyl containing α,β-unsaturated ketone, Brown allylation, and ring-closing metathesis reaction.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 135716 |
| Deposited On: | 10 Aug 2023 10:36 |
| Last Modified: | 10 Aug 2023 10:36 |
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