Kumar Dey, Sujit ; Ataur Rahman, Mohammad ; Alkhazim Alghamdi, Ahmad ; Reddy, Basi V. Subba ; Yadav, Jhillu S. (2016) A Short and Efficient Approach for the Total Synthesis of (S)-Zearalenone and (R)-De-O-methyllasiodiplodin by Using Stille and RCM Protocols European Journal of Organic Chemistry, 2016 (9). pp. 1684-1692. ISSN 1434-193X
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Official URL: http://doi.org/10.1002/Ejoc.201501545
Related URL: http://dx.doi.org/10.1002/Ejoc.201501545
Abstract
A concise, flexible, and linear approach has been devised for the total synthesis of the resorcinylic acid lactones (S)-zearalenone (2) and (R)-de-O-methyllasiodiplodin (4) by using a Stille cross-coupling strategy. The other key steps of the synthesis include a ring-closing metathesis (RCM), a chemoselective reduction of an α,β-unsaturated ketone, and a transesterification reaction.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley & Sons, Inc. |
| ID Code: | 135707 |
| Deposited On: | 10 Aug 2023 10:22 |
| Last Modified: | 10 Aug 2023 10:22 |
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