An Efficient Stereoselective Synthesis of Key Fragments of Elaiophylin

Padmaja, Pannala ; Reddy, Pedavenkatagari Narayana ; Yadav, Jhillu Singh (2016) An Efficient Stereoselective Synthesis of Key Fragments of Elaiophylin Helvetica Chimica Acta, 99 (7). pp. 506-512. ISSN 0018-019X

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Official URL: http://doi.org/10.1002/Hlca.201600006

Related URL: http://dx.doi.org/10.1002/Hlca.201600006

Abstract

The stereoselective synthesis of key fragments 3 and 7 of elaiophylin has been accomplished from readily available epichlorohydrin as the starting material. The key reactions involved are Jacobsen's kinetic resolution, Prins cyclization, pyridinium chlorochromate-mediated oxidative cleavage, Grignard reaction, and cross-metathesis reaction.

Item Type:Article
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ID Code:135704
Deposited On:10 Aug 2023 10:12
Last Modified:10 Aug 2023 10:12

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