Yadav, Jhillu Singh ; Chinnam, Vijaya Vardhan ; Das, Saibal (2016) Studies towards the total synthesis of (+)-13-deoxytedanolide: stereoselective synthesis of C1–C9 and C9–C17 fragments Tetrahedron Letters, 57 (7). pp. 728-731. ISSN 0040-4039
Full text not available from this repository.
Official URL: http://doi.org/10.1016/J.Tetlet.2015.12.101
Related URL: http://dx.doi.org/10.1016/J.Tetlet.2015.12.101
Abstract
A facile and stereoselective synthesis of C1–C9 and C9–C17 fragments of (+)-13-deoxytedanolide and studies towards the synthesis of (+)-13-deoxytedanolide was accomplished in 20 linear steps. The key transformations of fragment 6 are Sharpless asymmetric dihydroxylation and preparation of terminal olefin from primary alcohol utilising organo selenium reaction. The key transformations of fragment 7 are from Sharpless epoxidation and Crimmin’s syn aldol chemistry.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 135702 |
| Deposited On: | 10 Aug 2023 10:09 |
| Last Modified: | 10 Aug 2023 10:09 |
Repository Staff Only: item control page
