Yadav, Jhillu S. ; Dutta, Palash (2016) Total Synthesis of a Diacetonide Derivative of Thuggacin A Journal of Organic Chemistry, 81 (5). pp. 1786-1797. ISSN 0022-3263
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Official URL: http://doi.org/10.1021/acs.joc.5b02426
Related URL: http://dx.doi.org/10.1021/acs.joc.5b02426
Abstract
A highly stereoselective total synthesis of the diacetonide derivative of the antibiotic thuggacin A has been described. The synthesis features the stereoselective Stille cross-coupling reaction to set up the whole carbon framework, aldol condensation to construct the highly substituted conjugated diene, non-Evans syn aldol, CBS reduction, Hantzsch's thiazole synthesis, Horner-Wadsworth-Emmons reaction, and Shiina's macrolactonization.
Item Type: | Article |
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Source: | Copyright of this article belongs to American Chemical Society. |
ID Code: | 135698 |
Deposited On: | 10 Aug 2023 09:43 |
Last Modified: | 10 Aug 2023 09:43 |
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