Bhavani, Kanugula ; GyanChander, Eppa ; Das, Saibal ; Yadav, Jhillu Singh (2018) Studies towards the Total Synthesis of Aspergillide‐B ChemistrySelect, 3 (12). pp. 3391-3393. ISSN 2365-6549
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Official URL: http://doi.org/10.1002/slct.201800181
Related URL: http://dx.doi.org/10.1002/slct.201800181
Abstract
A formal, stereoselective synthesis of Aspergillide-B is described. A highly diastereoselective Pd(0)-B(OPh)3 mediated syn-vic-diol formation from epoxy unsaturated ester used for the creation of C3-C4 centres. Iodine catalyzed allylation used for synthesis of trans-2,6-disubstitutedtetrahydro-2H-Pyran. Cross- metathesis, Yamaguchi macrolactonization are the other key features of the synthesis.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley & Sons, Inc. |
| ID Code: | 135681 |
| Deposited On: | 10 Aug 2023 07:33 |
| Last Modified: | 10 Aug 2023 07:33 |
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