Yadav, Jhillu ; Vardhan, Vijaya ; Das, Saibal (2014) Total Synthesis of 4-Ketoclonostachydiol Synthesis, 46 (17). pp. 2347-2352. ISSN 0039-7881
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Official URL: http://doi.org/10.1055/S-0033-1339121
Related URL: http://dx.doi.org/10.1055/S-0033-1339121
Abstract
A facile total synthesis of nonsymmetrical 14-membered macrocyclic bis-lactone, 4-ketoclonostachydiol has been demonstrated in a convergent approach. The synthetic strategy has been unambiguously successful towards incorporating all the three stereogenic centers present in the molecule with an overall yield of 0.9%. The key synthetic step includes MacMillan hydroxylation and Grubbs ring-closing metathesis reactions to furnish the core skeleton.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Georg Thieme Verlag KG. |
| ID Code: | 135663 |
| Deposited On: | 17 Jul 2023 08:02 |
| Last Modified: | 17 Jul 2023 08:02 |
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