Jemmis, Eluvathingal D. ; Jayasree, Elambalassery G. (2003) The rearrangement of dicarboranyl methyl cation: a possible synthetic strategy toward cationic closo-tricarbaboranes Inorganic Chemistry, 42 (24). pp. 7725-7727. ISSN 0020-1669
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ic035178b
Related URL: http://dx.doi.org/10.1021/ic035178b
Abstract
A quantitative study on cationic closo-tricarbaboranes proved their stability and a possible use for them as weakly coordinating ions due to the dispersal of positive charge throughout the cage. The current study explores computationally a synthetic strategy toward their realization in parallel with the benzyl cation-tropylium ion rearrangement. This study shows that cage expansion along with the incorporation of a carbon atom into the cage starting from the dicarboranyl methyl cation is in the realm of the possible. The rearrangements are found to have favorable energy barriers with one transition state. The geometry of the dicarboranyl methyl cations (benzyl cation analogues) with bent CH2 groups favors the rearrangement into the tropylium analogues. Thus, the comparison of well-known benzyl ion-tropylium ion rearrangement with similar reactions among polyhedral boranes unravels the feasibility of cationic tricarboranes.
Item Type: | Article |
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Source: | Copyright of this article belongs to American Chemical Society. |
ID Code: | 13502 |
Deposited On: | 12 Nov 2010 15:27 |
Last Modified: | 04 Jun 2011 05:48 |
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