Kumari, Namita ; Jha, Satadru ; Bhattacharya, Santanu (2011) Colorimetric Probes Based on Anthraimidazolediones for Selective Sensing of Fluoride and Cyanide Ion via Intramolecular Charge Transfer Journal of Organic Chemistry, 76 (20). pp. 8215-8222. ISSN 0022-3263
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Official URL: http://doi.org/10.1021/jo201290a
Related URL: http://dx.doi.org/10.1021/jo201290a
Abstract
Probes based on anthra[1,2-d]imidazole-6,11-dione were designed and synthesized for selective ion sensing. Each probe acted as strong colorimetric sensors for fluoride and cyanide ions and exhibited intramolecular charge transfer (ICT) band, which showed significant red-shifts after addition of either the F(-) or CN(-) ion. One of the probes (2) showed selective colorimetric sensing for both cyanide and fluoride ions. In organic medium, 2 showed selective color change with fluoride and cyanide, whereas in aqueous organic medium it showed a ratiometric response selectively for cyanide ion.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 134084 |
| Deposited On: | 03 Jan 2023 11:51 |
| Last Modified: | 03 Jan 2023 11:51 |
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