Das, Subhabrata ; Bhowmick, Tandra ; Punniyamurthy, T. ; Dey, Deepa ; Nath, Jayashree ; Chaudhuri, Mihir K. (2003) Molybdenum(VI)-peroxo complex catalyzed oxidation of alkylbenzenes with hydrogen peroxide Tetrahedron Letters, 44 (26). pp. 4915-4917. ISSN 00404039
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Official URL: http://doi.org/10.1016/S0040-4039(03)01126-2
Related URL: http://dx.doi.org/10.1016/S0040-4039(03)01126-2
Abstract
The molybdenum(VI) peroxo complex 1, synthesized from the reaction of MoO3 with H2O2 and 3,5-dimethylpyrazole (dmpz), selectively oxidizes benzylic C-H bonds of alkylbenzenes to the corresponding alcohols and ketones in moderate to good yields in the presence of H2O2 in acetonitrile under reflux (ca. 80°C).
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science Ltd |
| Keywords: | alkylbenzene;selective oxidation;molybdenum peroxo complex;hydrogen peroxide |
| ID Code: | 134071 |
| Deposited On: | 03 Jan 2023 10:08 |
| Last Modified: | 03 Jan 2023 10:08 |
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