Borax-Catalyzed and pH-Controlled Selective Oxidation of Organic Sulfides by H2O2: An Environmentally Clean Protocol

Hussain, Sahid ; Bharadwaj, Saitanya K. ; Pandey, Ravindra ; Chaudhuri, Mihir K. (2009) Borax-Catalyzed and pH-Controlled Selective Oxidation of Organic Sulfides by H2O2: An Environmentally Clean Protocol European Journal of Organic Chemistry, 2009 (20). pp. 3319-3322. ISSN 1434193X

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Official URL: http://doi.org/10.1002/ejoc.200900265

Related URL: http://dx.doi.org/10.1002/ejoc.200900265

Abstract

The selective oxidation of sulfides to sulfoxides and sulfones was achieved in high yields at room temperature with borax as a recyclable catalyst and H2O2 as the terminal oxidant by varying the pH of the reaction medium. The borax/H2O2 system can chemoselectively oxidize alkyl and aryl sulfides in the presence of oxidation-prone functional groups such as C=C, –CN, and –OH.

Item Type:Article
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Deposited On:03 Jan 2023 09:16
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