Garg, A. N. ; Goel, P. S. (1969) Mossbauer effect evidence of hydrogen bonding in ferrocyanic acid Journal of Inorganic and Nuclear Chemistry, 31 (3). pp. 697-702. ISSN 0022-1902
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002219...
Related URL: http://dx.doi.org/10.1016/0022-1902(69)80015-1
Abstract
Mossbauer spectra of anhydrous ferrocyanic acid, H4Fe(CN)6, and other alkali metal ferrocyanides have been studied. A definite quadrupole splitting (ΔEQ) is observed for H4Fe(CN)6 at 292 and 80°K. It is attributed to the presence of hydrogen bonding between the cyanide ligands as already suggested by the i.r., crystallographic and refractometric studies. The isomer shift (δ) decreases with increase in electronegativity indicating a corresponding decrease in 3d-electron density around the iron nucleus.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 13293 |
| Deposited On: | 11 Nov 2010 08:12 |
| Last Modified: | 02 Jun 2011 10:19 |
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