Reversible Mechanical Interlocking of D‐Shaped Molecular Karabiners bearing Coordination‐Bond Loaded Gates: Route to Self‐Assembled [2]Catenanes

Prusty, Soumyakanta ; Krishnaswamy, Shobhana ; Bandi, Sreenivasulu ; Chandrika, Baby ; Luo, Jingwei ; McIndoe, J. Scott ; Hanan, Garry S. ; Chand, Dillip Kumar (2015) Reversible Mechanical Interlocking of D‐Shaped Molecular Karabiners bearing Coordination‐Bond Loaded Gates: Route to Self‐Assembled [2]Catenanes Chemistry - A European Journal, 21 (43). pp. 15174-15187. ISSN 0947-6539

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Official URL: http://doi.org/10.1002/chem.201502394

Related URL: http://dx.doi.org/10.1002/chem.201502394

Abstract

Interlock game: A series of D-shaped self-assembled molecules are prepared from a three-component mixture of cis-protected PdII, rigid rod-like and flexible C-shaped ligands in a 2:1:1 ratio in DMSO. These molecules are considered as molecular karabiners bearing coordination bond loaded gates. The D-shaped molecules are interlocked in aqueous conditions, forming the corresponding [2]catenanes

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ID Code:131843
Deposited On:09 Dec 2022 04:56
Last Modified:09 Dec 2022 04:56

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