Mondal, Bijan ; Mondal, Bijnaneswar ; Pal, Koushik ; Varghese, Babu ; Ghosh, Sundargopal (2015) An electron-poor di-molybdenum triple-decker with a puckered [B4Ru2] bridging ring is an oblato-closo cluster Chemical Communications, 51 (18). pp. 3828-3831. ISSN 1359-7345
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Official URL: http://doi.org/10.1039/c4cc09630d
Related URL: http://dx.doi.org/10.1039/c4cc09630d
Abstract
An unprecedented, 22-valence-electron triple-decker sandwich complex [(Cp*Mo)2{μ-η6:η6-B4H4Ru2(CO)6}], 2, has been prepared. In an effort to generate analogous triple-deckers with group 6 metal carbonyl fragments in the middle deck, we have isolated [(Cp*MoCO)2(μ-H)2B4H4], 3, that provides the first direct evidence for the missing link between [(Cp*MoCl)2B3H7] and [(Cp*Mo)2B5H9] clusters.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 131805 |
| Deposited On: | 08 Dec 2022 09:52 |
| Last Modified: | 08 Dec 2022 09:52 |
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