Tripathy, Debakanta ; Sahoo, Himansu S. ; Ramkumar, Venkatachalam ; Chand, Dillip Kumar (2014) Palladium(ii) induced complete conformational enrichment of the syn isomer of N,N′-bis(4-pyridylformyl)piperazine RSC Advances, 4 (36). p. 18595. ISSN 2046-2069
Full text not available from this repository.
Official URL: http://doi.org/10.1039/c3ra47904h
Related URL: http://dx.doi.org/10.1039/c3ra47904h
Abstract
In the solution state, an equimolar mixture of syn- and anti-conformations is present for the ligand N,N′-bis(4-pyridylformyl)piperazine, L. Combining L with cis-Pd(en)(NO3)2 resulted in the formation of metallomacrocycle cis-[Pd2(en)2(L)2](NO3)4, 1, quantitatively. Coordinated L in complex 1 was found to exist exclusively in the syn-conformation. The equimolar mixture of syn- and anti-conformations was re-established by ethylenediamine induced demetallation of 1.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 131685 |
| Deposited On: | 07 Dec 2022 11:11 |
| Last Modified: | 07 Dec 2022 11:11 |
Repository Staff Only: item control page
