Sivakumari, Thakkellapati ; Preetha, Radhakrishnan ; Chadha, Anju (2014) Enantioselective oxidation of secondary alcohols by Candida parapsilosis ATCC 7330 RSC Advances, 4 (5). pp. 2257-2262. ISSN 2046-2069
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Official URL: http://doi.org/10.1039/c3ra46206d
Related URL: http://dx.doi.org/10.1039/c3ra46206d
Abstract
Optically pure allylic alcohols and 4-phenylbutan-2-ols were prepared by oxidative kinetic resolution using whole cells of Candida parapsilosis ATCC 7330. Only the ‘S’ enantiomer is selectively oxidized to the corresponding keto compound (yield, 37–46%) leaving the ‘R’ alcohol (yield, 37–52% and ee 46 to >99%). The biocatalytic method is carried out under mild conditions at 20 °C, pH 6.5 in phosphate buffer.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 131676 |
| Deposited On: | 07 Dec 2022 11:02 |
| Last Modified: | 07 Dec 2022 11:02 |
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