Mac, Dinh Hung ; Sattar, Abdul ; Chandrasekhar, Srivari ; Yadav, Jhillu Singh ; Grée, René (2012) Synthesis of new 4-methyl-3-piperidones via an iron-catalyzed intramolecular tandem isomerization–aldolisation process Tetrahedron, 68 (43). pp. 8863-8868. ISSN 00404020
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Official URL: http://doi.org/10.1016/j.tet.2012.08.048
Related URL: http://dx.doi.org/10.1016/j.tet.2012.08.048
Abstract
A new versatile synthesis of 3-piperidones is described, starting from amino acids. It uses, as a key step, an iron carbonyl-mediated intramolecular tandem isomerization–aldolisation reaction. These new heterocycles appear as useful scaffolds for the total synthesis of various types of bioactive molecules.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Ltd |
| Keywords: | Piperidines;Alkaloids;Azasugars;Iron pentacarbonyl;Catalysis;Tandem reactions |
| ID Code: | 131350 |
| Deposited On: | 06 Dec 2022 10:58 |
| Last Modified: | 06 Dec 2022 10:58 |
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