Gouthami, Pashikanti ; Chegondi, Rambabu ; Chandrasekhar, Srivari (2016) Formal Total Synthesis of (±)-Cephalotaxine and Congeners via Aryne Insertion Reaction Organic Letters, 18 (9). pp. 2044-2046. ISSN 1523-7060
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Official URL: http://doi.org/10.1021/acs.orglett.6b00659
Related URL: http://dx.doi.org/10.1021/acs.orglett.6b00659
Abstract
The formal total synthesis of pentacyclic core alkaloid, (±)-cephalotaxine is achieved in nine steps from known 2-allylpyrrolidine-2-carboxaldehyde using aryne insertion reaction as a key step in 10% overall yield. The developed novel strategy enabled easy access to cephalotaxine congeners
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society |
| ID Code: | 131312 |
| Deposited On: | 06 Dec 2022 09:57 |
| Last Modified: | 06 Dec 2022 09:57 |
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