Pal, Pranesh ; Mainkar, Prathama S. ; Nayani, Kiranmai ; Chandrasekhar, Srivari (2020) Mn-catalyzed radical initiated domino transformation of alkynylated cyclohexadienones with TMSN3 and O2 to bicyclic azido alcohols Chemical Communications, 56 (23). pp. 3453-3456. ISSN 1359-7345
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Official URL: http://doi.org/10.1039/D0CC00102C
Related URL: http://dx.doi.org/10.1039/D0CC00102C
Abstract
An efficient Mn-catalyzed cascade azide radical addition/cyclization/oxygen insertion reaction of alkyne-tethered cyclohexadienones with TMSN3 under mild conditions is reported. This domino reaction presents good diastereoselectivity generating bicyclic azido alcohol scaffolds which can be transformed into useful building blocks in organic synthesis for medicinal chemistry.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry |
| ID Code: | 131279 |
| Deposited On: | 06 Dec 2022 08:56 |
| Last Modified: | 06 Dec 2022 08:56 |
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