Pulukuri, Kiran Kumar ; Chakraborty, Tushar Kanti (2012) Stereoselective Synthesis of the Monomeric Unit of Actin Binding Macrolide Rhizopodin Organic Letters, 14 (11). pp. 2858-2861. ISSN 1523-7060
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Official URL: http://doi.org/10.1021/ol301103d
Related URL: http://dx.doi.org/10.1021/ol301103d
Abstract
An efficient, scalable, and stereocontrolled synthesis of the entire carbon framework of an actin binding dimeric macrolide rhizopodin has been accomplished in its protected form. The key features of our synthesis include a titanium catalyzed anti acetal aldol reaction, a substrate controlled diastereoslelective prenyl stannylation, a Mukaiyama aldol reaction, an indium mediated diastereoselective propargylation, and an advanced stage Stille coupling reaction.
Item Type: | Article |
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Source: | Copyright of this article belongs to American Chemical Society |
ID Code: | 131123 |
Deposited On: | 02 Dec 2022 11:12 |
Last Modified: | 02 Dec 2022 11:12 |
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