Peptidomimetics with tunable tertiary amide bond containing substituted β-proline and β-homoproline

Basu, Sandip ; Kandiyal, Pancham Singh ; Neelamraju, Venkata Suresh Kumar ; Singh, Harjinder ; Ampapathi, Ravi Sankar ; Chakraborty, Tushar Kanti (2014) Peptidomimetics with tunable tertiary amide bond containing substituted β-proline and β-homoproline Tetrahedron, 70 (6). pp. 1169-1175. ISSN 00404020

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Official URL: http://doi.org/10.1016/j.tet.2013.12.078

Related URL: http://dx.doi.org/10.1016/j.tet.2013.12.078

Abstract

Tunable cis/trans prolyl amide bond configuration in substituted β-proline (β-Pro) and β-homoproline (β-Hpro) homodimers was explored, based on position and nature of the substituent. Tertiary amide bond in β-proline (β2,3-substituted) dimers show distinct trans configuration and β-homoproline (β3-substituted) dimers preferably exhibited cis configuration.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Ltd
Keywords:Peptidomimetics;β-Proline and β-homoproline;cis–trans Isomerization;2D-NMRDFT
ID Code:131113
Deposited On:02 Dec 2022 11:02
Last Modified:02 Dec 2022 11:02

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