An overview of the recent synthetic studies toward penifulvins and other fenestranes

Das, Dipendu ; Chakraborty, Tushar Kanti (2016) An overview of the recent synthetic studies toward penifulvins and other fenestranes Tetrahedron Letters, 57 (33). pp. 3665-3677. ISSN 00404039

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Official URL: http://doi.org/10.1016/j.tetlet.2016.07.011

Related URL: http://dx.doi.org/10.1016/j.tetlet.2016.07.011

Abstract

Complex natural products provide a useful template for the construction of novel molecular scaffolds of biological as well as theoretical interest. In this regard, fenestranes have emerged as a challenging target for organic chemists. The existence of the planarized distortion of the central quaternary carbon in fenestranes away from its standard tetrahedral bond angle makes their synthesis a daunting task. In this review, an attempt has been made to capture the essence of some recent synthetic studies toward these molecules with an emphasis on penifulvins, the first [5.5.5.6]dioxafenestrane.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Ltd
Keywords:Penifulvin;Fenestrane;Titanocene;Radical cyclization;Asperaculin
ID Code:131096
Deposited On:02 Dec 2022 10:29
Last Modified:02 Dec 2022 10:29

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