A Novel Heterometallic μ9-Boride Cluster: Synthesis and Structural Characterization of [(η5-C5Me5Rh)2{Co6(CO)12}(μ-H)(BH)B]

Roy, Dipak Kumar ; Barik, Subrat Kumar ; Mondal, Bijan ; Varghese, Babu ; Ghosh, Sundargopal (2014) A Novel Heterometallic μ9-Boride Cluster: Synthesis and Structural Characterization of [(η5-C5Me5Rh)2{Co6(CO)12}(μ-H)(BH)B] Inorganic Chemistry, 53 (2). pp. 667-669. ISSN 0020-1669

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Official URL: http://doi.org/10.1021/ic4021178

Related URL: http://dx.doi.org/10.1021/ic4021178

Abstract

The preparation, characterization, and electronic structure of the first heterometallic μ9-boride cluster [(Cp*Rh)2{Co6(CO)12}(μ-H)(BH)B)] has been reported. The interstitial boron atom in the title cluster is within the bonding contact of eight metal and one boron atom in a unique tricapped trigonal prism geometry.

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ID Code:131001
Deposited On:02 Dec 2022 05:53
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