Bandi, Sreenivasulu ; Pal, Amlan K. ; Hanan, Garry S. ; Chand, Dillip Kumar (2014) Stoichiometrically Controlled Revocable Self-Assembled “Spiro” versus Quadruple-Stranded “Double-Decker” Type Coordination Cages Chemistry - A European Journal, 20 (41). pp. 13122-13126. ISSN 0947-6539
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Official URL: http://doi.org/10.1002/chem.201403808
Related URL: http://dx.doi.org/10.1002/chem.201403808
Abstract
Molecular double-decker cages: The simple combination of PdII with the tris-monodentate ligand bis(pyridin-3-ylmethyl) pyridine-3,5-dicarboxylate, L, at ratios of 1:2 and 3:4 demonstrated the stoichiometrically controlled formation of a “spiro-type” Pd1L2 macrocycle and a quadruple-stranded “double-decker” Pd3L4 cage, respectively. The architecture of the cage is a fresh design that has two compartments that can accommodate two units of fluoride, chloride or bromide ions, one in each enclosure. However, the entry of iodide is altogether restricted.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
| ID Code: | 130712 |
| Deposited On: | 29 Nov 2022 09:03 |
| Last Modified: | 29 Nov 2022 09:03 |
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