Chemical-Shift-Resolved19F NMR Spectroscopy between 13.5 and 135 MHz: Overhauser-DNP-Enhanced Diagonal Suppressed Correlation Spectroscopy

George, Christy ; Chandrakumar, Narayanan (2014) Chemical-Shift-Resolved19F NMR Spectroscopy between 13.5 and 135 MHz: Overhauser-DNP-Enhanced Diagonal Suppressed Correlation Spectroscopy Angewandte Chemie International Edition, 53 (32). pp. 8441-8444. ISSN 1433-7851

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Official URL: http://doi.org/10.1002/anie.201402320

Related URL: http://dx.doi.org/10.1002/anie.201402320

Abstract

Overhauser–DNP-enhanced homonuclear 2D 19F correlation spectroscopy with diagonal suppression is presented for small molecules in solution at moderate fields (13.5–135 MHz; DNP=dynamic nuclear polarization). At these relatively low fields, structural information is nevertheless accessible without a sensitivity penalty. This powerful general approach avoids the special requirements of high-field 19F NMR spectroscopy.

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ID Code:130649
Deposited On:29 Nov 2022 05:02
Last Modified:29 Nov 2022 05:02

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