Malik, Payal ; Chakraborty, Debashis (2013) Synthesis, structural and spectroscopic characterization of thiophosphorodiamidates and effect of ZnCl2 on the hydrolysis of the P–N bond Polyhedron, 52 . pp. 831-836. ISSN 0277-5387
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Official URL: http://doi.org/10.1016/j.poly.2012.07.033
Related URL: http://dx.doi.org/10.1016/j.poly.2012.07.033
Abstract
New N,N′-dibenzylthiophosphorodiamidate derivatives were synthesized from the corresponding thiophosphorodichloridate intermediates and benzylamine. Several compounds with formula 2-MeC6H4OP(S)(NHBn)2 (6), 2-FC6H4OP(S)(NHBn)2 (7), 2-ClC6H4OP(S)(NHBn)2 (8), 4-MeC6H4OP(S)(NHBn)2 (9) and 4-t-BuC6H4OP(S)(NHBn)2 (10) were synthesized and characterized by 1H, 13C, 31P NMR, IR, mass spectroscopy and elemental analysis. The single crystal X-ray diffraction studies of 6 and 7 have been described. ZnCl2 assisted P–N bond hydrolysis of thiophosphorodiamidates was investigated.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 130471 |
| Deposited On: | 25 Nov 2022 08:02 |
| Last Modified: | 25 Nov 2022 08:02 |
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