Bose, Shubhankar Kumar ; Roy, Dipak Kumar ; Shankhari, Pritam ; Yuvaraj, K. ; Mondal, Bijan ; Sikder, Amrita ; Ghosh, Sundargopal (2013) Syntheses and Characterization of New Vinyl-Borylene Complexes by the Hydroboration of Alkynes with [(μ3-BH)(Cp*RuCO)2(μ-CO)Fe(CO)3] Chemistry - A European Journal, 19 (7). pp. 2337-2343. ISSN 0947-6539
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Official URL: http://doi.org/10.1002/chem.201203627
Related URL: http://dx.doi.org/10.1002/chem.201203627
Abstract
Unique metal–borylene complexes: Photolysis of a triply bridged borylene complex [(μ3-BH)(Cp*RuCO)2(μ-CO)Fe(CO)3] (Cp*=η5-C5Me5) with various internal alkynes led to hydroboration yielding new vinyl-borylene complexes (see figure). A plausible mechanism has been proposed for the formation of vinyl-borylene complexes, which is supported by density functional theory (DFT) methods.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
| ID Code: | 130279 |
| Deposited On: | 24 Nov 2022 04:58 |
| Last Modified: | 24 Nov 2022 04:58 |
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