Basavaiah, Deevi ; Thamizharasi, Perumal (2017) Baylis-Hillman Reaction: In Situ Generated Isoquinolinium Species as Excellent Electrophiles for Coupling with Alkyl Acrylates and Acrylonitrile European Journal of Organic Chemistry, 2017 (34). pp. 5135-5140. ISSN 1434-193X
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Official URL: http://doi.org/10.1002/ejoc.201700743
Related URL: http://dx.doi.org/10.1002/ejoc.201700743
Abstract
Isoquinolinium species, generated in situ from 2-alkynylbenzaldehydes, arylamines, and silver trifluoromethanesulfonate (AgOTf), are utilized as excellent electrophiles for Baylis–Hillman coupling with alkyl acrylates and acrylonitrile in the presence of 1,4-diazabicyclo[2.2.2]octane (DABCO) to provide 1,2,3-trisubstituted dihydroisoquinoline derivatives.
Item Type: | Article |
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Source: | Copyright of this article belongs to John Wiley and Sons. |
ID Code: | 130145 |
Deposited On: | 02 Dec 2022 05:56 |
Last Modified: | 05 Dec 2022 05:56 |
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