Basak, Amit ; Mondal, Sayantan ; Mitra, Tapobrata ; Mukherjee, Raja ; Addy, Partha (2012) Garratt–Braverman Cyclization, a Powerful Tool for C–C Bond Formation Synlett, 23 (18). pp. 2582-2602. ISSN 0936-5214
Full text not available from this repository.
Official URL: http://doi.org/10.1055/S-0032-1317321
Related URL: http://dx.doi.org/10.1055/S-0032-1317321
Abstract
Development of new strategies for C–C bond formation remains in the forefront of organic synthesis. The base-mediated rearrangement of bis-propargyl sulfones via bis-allenes generated in situ, now known as the Garratt–Braverman cyclization (GBC), leads to the formation of two new C–C bonds. The reaction has recently drawn attention from organic chemists due to the wide scope as well as interesting mechanism. This report aims to give an account of the developments in this area with particular emphasis on synthetic applications.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers Inc. |
| Keywords: | Alkynes; Ayclizations; ene reactions; polyclyclic compounds; radicals ;sulfones |
| ID Code: | 129900 |
| Deposited On: | 02 Dec 2022 06:05 |
| Last Modified: | 05 Dec 2022 05:30 |
Repository Staff Only: item control page
