Purohit, Priyank ; Seth, Kapileswar ; Kumar, Asim ; Chakraborti, Asit K. (2017) C–O Bond Activation by Nickel–Palladium Hetero-Bimetallic Nanoparticles for Suzuki–Miyaura Reaction of Bioactive Heterocycle-Tethered Sterically Hindered Aryl Carbonates ACS Catalysis, 7 (4). pp. 2452-2457. ISSN 2155-5435
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Official URL: http://doi.org/10.1021/acscatal.6b02912
Related URL: http://dx.doi.org/10.1021/acscatal.6b02912
Abstract
Ni–Pd binary nanoclusters are reported for the activation of the C–O bond for Suzuki–Miyaura cross-coupling of bioactive heterocycle-tethered sterically hindered aryl carbonates with aryl boronic acids. The reaction does not take place in the presence of either the Pd or Ni salts/complexes or the individual Pd or Ni nanoparticles, indicating ensembling cooperativity between the Pd and Ni nanoparticles in activating the C–O bond.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society |
| ID Code: | 129389 |
| Deposited On: | 16 Nov 2022 05:56 |
| Last Modified: | 16 Nov 2022 05:56 |
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