The Reaction of Huisgen Zwitterion with Diaryl-1,2-diones and Ketones: An Efficient Protocol for Carbon-Nitrogen Bond Formation

Nair, Vijay ; Biju, A. ; Mathew, Smitha (2007) The Reaction of Huisgen Zwitterion with Diaryl-1,2-diones and Ketones: An Efficient Protocol for Carbon-Nitrogen Bond Formation Synthesis, 2007 (5). pp. 697-704. ISSN 0039-7881

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Official URL: http://doi.org/10.1055/s-2007-965910

Related URL: http://dx.doi.org/10.1055/s-2007-965910

Abstract

The reaction of Huisgen zwitterion, derived from triphenylphosphine and dialkyl azodicarboxylate, with diaryl-1,2-diones afforded N,N-dicarboalkoxy monohydrazones via a mechanistically novel rearrangement. Cyclic and acyclic ketones furnished vinyl hydrazinedicarboxylates under similar conditions.

Item Type:Article
Source:Copyright of this article belongs to Georg Thieme Verlag KG
ID Code:128747
Deposited On:03 Nov 2022 06:57
Last Modified:03 Nov 2022 06:57

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