Biju, Akkattu T. ; Wurz, Nathalie E. ; Glorius, Frank (2010) N-Heterocyclic Carbene-Catalyzed Cascade Reaction Involving the Hydroacylation of Unactivated Alkynes Journal of the American Chemical Society, 132 (17). pp. 5970-5971. ISSN 0002-7863
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Official URL: http://doi.org/10.1021/ja102130s
Related URL: http://dx.doi.org/10.1021/ja102130s
Abstract
The N-heterocyclic carbene (NHC)-catalyzed hydroacylation of unactivated alkynes to provide alpha,beta-unsaturated ketones is reported. In addition, a rare case of an efficient and selective dually NHC-catalyzed cascade reaction involving the hydroacylation of alkynes and a subsequent intermolecular Stetter reaction allows the formation of chromanones containing a 1,4-diketone moiety.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society |
| ID Code: | 128732 |
| Deposited On: | 03 Nov 2022 06:56 |
| Last Modified: | 03 Nov 2022 06:56 |
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