Padmanaban, Mohan ; Biju, Akkattu T. ; Glorius, Frank (2011) Efficient Synthesis of Benzofuranones: N-Heterocyclic Carbene (NHC)/Base-Catalyzed Hydroacylation–Stetter–Rearrangement Cascade Organic Letters, 13 (20). pp. 5624-5627. ISSN 1523-7060
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Official URL: http://doi.org/10.1021/ol2023483
Related URL: http://dx.doi.org/10.1021/ol2023483
Abstract
A N-heterocyclic carbene/base-catalyzed cascade reaction leading to the formation of functionalized benzofuranones is reported. The reaction proceeds via an intramolecular hydroacylation of unactivated alkynes followed by an intermolecular Stetter reaction and a base-catalyzed chromanone to benzofuranone rearrangement.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society |
| ID Code: | 128721 |
| Deposited On: | 03 Nov 2022 06:54 |
| Last Modified: | 03 Nov 2022 06:54 |
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