Bhunia, Anup ; Roy, Tony ; Gonnade, Rajesh G. ; Biju, Akkattu T. (2014) Rapid Access to Benzoxaphospholes and Their Spiro Analogues by a Three-Component Coupling Involving Arynes, Phosphines, and Activated Ketones Organic Letters, 16 (19). pp. 5132-5135. ISSN 1523-7060
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Official URL: http://doi.org/10.1021/ol502490t
Related URL: http://dx.doi.org/10.1021/ol502490t
Abstract
An operationally simple multicomponent coupling involving in situ generated arynes from 2-(trimethylsilyl)aryl triflates, phosphines, and various acyclic and cyclic activated carbonyl compounds has been developed. The reaction proceeds via a formal [3 + 2] cycloaddition mode giving access to differently substituted (spiro)benzoxaphosphole derivatives in moderate to good yields. Mild reaction conditions, a broad scope, and the possibility of varying all the three-components are the notable features of the present reaction.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society |
| ID Code: | 128679 |
| Deposited On: | 03 Nov 2022 06:53 |
| Last Modified: | 03 Nov 2022 06:53 |
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