Thangaraj, Manikandan ; Bhojgude, Sachin Suresh ; Mane, Manoj V. ; Biju, Akkattu T. (2016) From insertion to multicomponent coupling: temperature dependent reactions of arynes with aliphatic alcohols Chemical Communications, 52 (8). pp. 1665-1668. ISSN 1359-7345
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Official URL: http://doi.org/10.1039/C5CC08307A
Related URL: http://dx.doi.org/10.1039/C5CC08307A
Abstract
The temperature dependent selectivity switch in the reaction of arynes with aliphatic alcohols in THF has been reported. At −20 °C, arynes smoothly insert into the O–H bond of alcohols to form alkyl aryl ethers. Interestingly, at 60 °C, a highly selective multicomponent coupling occurs with the solvent THF acting as the nucleophilic trigger affording (4-(alkoxy)butoxy)arenes.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry |
| ID Code: | 128664 |
| Deposited On: | 03 Nov 2022 06:52 |
| Last Modified: | 03 Nov 2022 06:52 |
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