Bhattacharjee, Subrata ; Deswal, Shiksha ; Manoj, Niket ; Jindal, Garima ; Biju, Akkattu T. (2021) Aryne Three-Component Coupling Involving CS2 for the Synthesis of S-Aryl Dithiocarbamates Organic Letters, 23 (23). pp. 9083-9088. ISSN 1523-7060
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Official URL: http://doi.org/10.1021/acs.orglett.1c03378
Related URL: http://dx.doi.org/10.1021/acs.orglett.1c03378
Abstract
A facile synthesis of biologically important S-aryl dithiocarbamates has been demonstrated by the aryne three-component coupling involving CS2 and aliphatic amines. This transition-metal-free and mild reaction is scalable and operates with good functional group compatibility. Preliminary mechanistic experiments, including density functional theory studies, are also provided. Moreover, with 3-triflyloxybenzynes, a unique four-component coupling incorporating tetrahydrofuran was observed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society |
| ID Code: | 128580 |
| Deposited On: | 03 Nov 2022 06:43 |
| Last Modified: | 03 Nov 2022 06:43 |
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