Chung, In ; Biswas, Kanishka ; Song, Jung-Hwan ; Androulakis, John ; Chondroudis, Konstantinos ; Paraskevopoulos, Konstantinos M. ; Freeman, Arthur J. ; Kanatzidis, Mercouri G. (2011) Rb4Sn5P4Se20: A Semimetallic Selenophosphate Angewandte Chemie International Edition, 50 (38). pp. 8834-8838. ISSN 14337851
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Official URL: http://doi.org/10.1002/anie.201104050
Related URL: http://dx.doi.org/10.1002/anie.201104050
Abstract
Moonlight metal: The valence-precise compound Rb4Sn5P4Se20 (see picture, Rb blue, Sn green, P black, Se red) is the first metallic selenophosphate. It features a new structure hybrid of “conducting” [Sn5Se8] layers and “insulating” [P2Se6] ligands. It shows the highest electrical conductivity among the chalcophosphates and an extremely low thermal conductivity of 0.44 W m−1 K−1 at room temperature.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley & Sons, Inc. |
| ID Code: | 128232 |
| Deposited On: | 03 Nov 2022 05:52 |
| Last Modified: | 03 Nov 2022 05:52 |
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