Localized Vibrations of Bi Bilayer Leading to Ultralow Lattice Thermal Conductivity and High Thermoelectric Performance in Weak Topological Insulator n-Type BiSe

Samanta, Manisha ; Pal, Koushik ; Pal, Provas ; Waghmare, Umesh V. ; Biswas, Kanishka (2018) Localized Vibrations of Bi Bilayer Leading to Ultralow Lattice Thermal Conductivity and High Thermoelectric Performance in Weak Topological Insulator n-Type BiSe Journal of the American Chemical Society, 140 (17). pp. 5866-5872. ISSN 0002-7863

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Official URL: http://doi.org/10.1021/jacs.8b02691

Related URL: http://dx.doi.org/10.1021/jacs.8b02691

Abstract

Realization of high thermoelectric performance in n-type semiconductors is of imperative need on account of the dearth of efficient n-type thermoelectric materials compared to the p-type counterpart. Moreover, development of efficient thermoelectric materials based on Te-free compounds is desirable because of the scarcity of Te in the Earth’s crust. Herein, we report the intrinsic ultralow thermal conductivity and high thermoelectric performance near room temperature in n-type BiSe, a Te-free solid, which recently has emerged as a weak topological insulator. BiSe possesses a layered structure consisting of a bismuth bilayer (Bi2) sandwiched between two Bi2Se3 quintuple layers [Se–Bi–Se–Bi-Se], resembling natural heterostructure. High thermoelectric performance of BiSe is realized through the ultralow lattice thermal conductivity (κlat of ∼0.6 W/mK at 300 K), which is significantly lower than that of Bi2Se3 (κlat of ∼1.8 W/mK at 300 K), although both of them belong to the same layered homologous family (Bi2)m(Bi2Se3)n. Phonon dispersion calculated from first-principles and the experimental low-temperature specific heat data indicate that soft localized vibrations of bismuth bilayer in BiSe are responsible for its ultralow κlat. These low energy optical phonon branches couple strongly with the heat carrying acoustic phonons, and consequently suppress the phonon mean free path leading to low κlat. Further optimization of thermoelectric properties of BiSe through Sb substitution and spark plasma sintering (SPS) results in high ZT ∼ 0.8 at 425 K along the pressing direction, which is indeed remarkable among Te-free n-type thermoelectric materials near room temperature.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society
ID Code:128090
Deposited On:03 Nov 2022 05:45
Last Modified:18 Aug 2023 11:29

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