Manthiram, A. ; Gopalakrishnan, J. (1980) New A2+Mo4+O3 oxides with defect spinel structure Materials Research Bulletin, 15 (2). pp. 207-211. ISSN 0025-5408
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002554...
Related URL: http://dx.doi.org/10.1016/0025-5408(80)90121-X
Abstract
New A2+Mo4+O3 oxides for A = Mn, Co and Zn crystallizing in a defect spinel structure have been prepared by hydrogen-reduction of the corresponding AMoO4 oxides. X-ray powder diffraction intensity analysis of the zinc compound indicates that the cation distribution is (Zn)t[Zn1/3Mo4/31/3]oO4 . The defect spinels are metastable decomposing to a mixture of A2Mo3O8 and AO at high temperatures. Electrical and magnetic properties of the spinel phases are reported.
Item Type: | Article |
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Source: | Copyright of this article belongs to Elsevier Science. |
ID Code: | 12790 |
Deposited On: | 11 Nov 2010 08:56 |
Last Modified: | 03 Jun 2011 06:08 |
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