Iwamatsu, Sho-ichi ; Vijayalakshmi, Periya S. ; Hamajima, Masanori ; Suresh, Cherumuttathu H. ; Koga, Nobuaki ; Suzuki, Toshiyasu ; Murata, Shizuaki (2002) A Novel Photorearrangement of a Cyclohexadiene Derivative of C60 Organic Letters, 4 (7). pp. 1217-1220. ISSN 1523-7060
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Official URL: http://doi.org/10.1021/ol025678t
Related URL: http://dx.doi.org/10.1021/ol025678t
Abstract
Photorearrangement of tetraalkoxycarbonyl-substituted cyclohexadiene derivatives of C60 yields not only well-known bis(fulleroid) but also bis(methano)fullerene. Existence of a labile and structurally new intermediate is observed in the reaction mixture. The discovery of the compound suggests the existence of another possible pathway giving those two products other than the widely accepted [4 + 4]/[2 + 2 + 2] mechanism.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society |
| ID Code: | 127633 |
| Deposited On: | 13 Oct 2022 10:57 |
| Last Modified: | 13 Oct 2022 10:57 |
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