Suresh, Cherumuttathu H. ; Baik, Mu-Hyun (2005) α,β-(C–C–C) Agostic bonds in transition metal based olefin metathesis catalyses Dalton Transactions (18). p. 2982. ISSN 1477-9226
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Official URL: http://doi.org/10.1039/B508192K
Related URL: http://dx.doi.org/10.1039/B508192K
Abstract
An α,β-(C–C–C) agostic bond is found to provide the additional stabilization needed to make the formally 14-electron metallacyclobutane intermediate lower in energy than its 16-electron alkylidene analogue during olefin metathesis catalysis.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry |
| ID Code: | 127597 |
| Deposited On: | 13 Oct 2022 10:56 |
| Last Modified: | 13 Oct 2022 10:56 |
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